- Ashleigh Barty (1) defeated qualifier Lucia Bronzetti 6-1 6-1
- Camila Giorgi (30) defeated Tereza Martincova 6-2 7-6(2)
- Amanda Anisimova defeated Belinda Bencic (22) 6-2 7-5
- Naomi Osaka (13) defeated Madison Brengle 6-0 6-4
- Nuria Parrizas Diaz received a walkover from Maryna Zanevska
- Jessica Pegula (21) defeated Bernarda Pera 6-4 6-4
- Veronika Kudermetova (28) defeated Elena-Gabriela Ruse 6-2 7-5
- Maria Sakkari (5) defeated qualifier Zheng Qinwen 6-1 6-4
- Barbora Krejcikova (4) defeated wildcard Wang Xiyu 6-2 6-3
- Jelena Ostapenko (26) defeated Alison Riske 4-6 6-2 6-4
- Victoria Azarenka (24) defeated Jil Teichmann 6-1 6-2
- Elina Svitolina (15) defeated Harmony Tan 6-3 5-7 5-1 (retired)
- Madison Keys defeated Jaqueline Cristian 6-2 7-5
- Wang Qiang defeated Alison Van Uytvanck 2-6 7-6(5) 6-3
- Marta Kostyuk defeated Sara Sorribes Tormo (32) 7-6(5) 6-3
- Paula Badosa (8) defeated qualifier Martina Trevisan 6-0 6-3
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