9th seed Ons Jabeur withdrew due to a back injury, and was replaced by lucky loser Irina Bara.
Zheng Saisai withdrew due to a wrist injury, and was replaced by lucky loser Nao Hibino.
- Ashleigh Barty (1) defeated qualifier Lesia Tsurenko 6-0 6-1
- Qualifier Lucia Bronzetti defeated Varvara Gracheva 3-6 6-2 6-3
- Tereza Martincova defeated Lauren Davis 7-5 6-2
- Camila Giorgi (30) defeated Anastasia Potapova 6-4 6-0
- Belinda Bencic (22) defeated Kristina Mladenovic 6-4 6-3
- Amanda Anisimova defeated qualifier Arianne Hartono 2-6 6-4 6-3
- Madison Brengle defeated Dayana Yastremska 6-1 0-6 5-0 (retired)
- Naomi Osaka (13) defeated Camila Osorio 6-3 6-3
- Nuria Parrizas Diaz defeated lucky loser Irina Bara 6-3 6-1
- Maryna Zanevska defeated Kaja Juvan 7-6(7) 7-6(4)
- Bernarda Pera defeated Ekaterina Alexandrova 7-5 6-3
- Jessica Pegula (21) defeated Anhelina Kalinina 4-6 7-6(1) 7-5
- Veronika Kudermetova (28) defeated Claire Liu 6-4 6-4
- Elena-Gabriela Ruse defeated Jasmine Paolini 6-1 6-3
- Qualifier Zheng Qinwen defeated Aliaksandra Sasnovich 6-3 1-6 7-6(10-5)
- Maria Sakkari (5) defeated Tatjana Maria 6-4 7-6(2)
- Barbora Krejcikova (4) defeated Andrea Petkovic 6-2 6-0
- Wildcard Wang Xiyu defeated qualifier Viktoria Kuzmova 7-5 6-3
- Alison Riske defeated Donna Vekic 6-2 6-2
- Jelena Ostapenko (26) defeated Anna Karolina Schmiedlova 6-7(7) 6-4 6-1
- Victoria Azarenka (24) defeated Panna Udvardy 6-3 6-1
- Jil Teichmann defeated Petra Martic 6-3 6-3
- Harmony Tan defeated Yulia Putintseva 6-3 6-3
- Elina Svitolina (15) defeated Fiona Ferro 6-1 7-6(4)
- Madison Keys defeated Sofia Kenin (11) 7-6(2) 7-5
- Jaqueline Cristian defeated Greet Minnen 7-5 6-4
- Alison Van Uytvanck defeated qualifier Cristina Bucsa 6-3 6-4
- Wang Qiang defeated CoCo Gauff (18) 6-4 6-2
- Sara Sorribes Tormo (32) defeated Kirsten Flipkens 6-4 6-1
- Marta Kostyuk defeated wildcard Diane Parry 6-1 7-6(2)
- Qualifier Martina Trevisan defeated lucky loser Nao Hibino 6-2 6-3
- Paula Badosa (8) defeated Ajla Tomljanovic 6-4 6-0
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