- Miomir Kecmanovic defeated Tommy Paul 7-6(7) 7-5 7-6(8)
- Lorenzo Sonego (25) defeated Oscar Otte 2-6 6-2 6-3 6-1
- Gaël Monfils (17) defeated Alexander Bublik 6-1 6-0 6-4
- Cristian Garin (16) defeated Pedro Martinez 6-7(1) 7-6(4) 2-6 6-2 6-2
- Sebastian Korda defeated Corentin Moutet 3-6 6-4 6-7(2) 7-5 7-6(10-6)
- Pablo Carreno Busta (19) defeated Tallon Griekspoor 6-3 6-7(6) 7-6(3) 3-6 6-4
- Carlos Alcaraz (31) defeated Dusan Lajovic 6-2 6-1 7-5
- Matteo Berrettini (7) defeated wildcard Stefan Kozlov 6-1 4-6 6-4 6-1
- Alexander Zverev (3) defeated John Millman 6-4 6-4 6-0
- Qualifier Radu Albot defeated wildcard Aleksandar Vukic 6-4 7-6(4) 6-4
- Reilly Opelka (23) defeated Dominik Koepfer 6-4 6-3 7-6(4)
- Denis Shapovalov (14) defeated Soonwoo Kwon 7-6(6) 6-7(3) 6-7(6) 7-5 6-2
- Adrian Mannarino defeated Hubert Hurkacz (10) 6-4 6-2 6-3
- Aslan Karatsev (18) defeated Mackenzie McDonald 3-6 6-2 6-2 6-3
- Karen Khachanov (28) defeated Benjamin Bonzi 6-4 6-0 7-5
- Rafael Nadal (6) defeated qualifier Yannick Hanfmann 6-2 6-3 6-4
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