Second round commenced in Rio de Janeiro.
2025 Rio Open presented by Claro, an ATP 500 tournament, on Clay Outdoor, Rio de Janeiro, Brazil, 17-23 February 2025.
Defending champion:
Sebastian Baez (5) who defeated qualifier Mariano Navone 6-2 6-1
Second round results:
- Alexander Zverev (1) defeated Alexander Shevchenko 7-6(1) 7-6(6)
- Francisco Comesana defeated Nicolas Jarry (6) 7-6(4) 6-7(1) 7-6(6)
- Sebastian Baez (5) defeated Mariano Navone 6-4 1-6 6-3
- Qualifier Tseng Chun-hsin defeated wildcard Thiago Monteiro 6-7(4) 6-3 7-6(4)
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